The Incorporation of Graphene to LiCoO2 as a Cathode to Improve the Performance of LIBs

Student: Kenan Wang

Degree: M.S., May 2018

Major Professor: Dr. Simon S. Ang

Research Area(s):

Microelectronics

Photonics

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Background/Relevance

  • Electric cars has huge potential in the future, but current Lithium ion batteries have not enough capacity used in electric cars.
  • Graphene has been widely used in several fields, and it shows great improvements to different applications.

Innovation

  • Incorporating graphene into cathode materials to test the performance of cathode.

Approach

  • Pristine cathode and cathode incorporated graphene were prepared first.
  • Many “half cells” were assembled in the glove box.
  • The electrochemical impedance spectroscopy measurements for “half cells” were achieved using a CHI660D Analyzer.
  • Full cycles of charging and discharging of sample cells were finished using a BT2000 Battery Tester

Key Results

  • Samples incorporated with 0.5 wt.% graphene sample has the largest discharge capacity compared with other samples.
  • Samples incorporated with 1 wt.% graphene show the most stable discharge capacity compared with other samples.
  • The incorporation of 2 wt.% graphene enhance the performance of cathode.

Conclusions

  • The incorporation of graphene enhance the battery performance with a LiCoO2 cathode.

Future Work

  • Further work could focus on adding higher weight percentages (>2 wt.%) of graphene powder into cathode materials to analyze the connection between different weight percentages of graphene powder added and the performance of lithium ion batteries.